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Updated: Dec 9, 2025

Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
Optimizing the Use of a Constrained Resource to Minimize Regional Greenhouse Gas Emissions: The Case Study of Slag in
Alessandro Arrigoni1, I Daniel Posen1, Heather L MacLean1
1Department of Civil and Mineral Engineering, University of Toronto, Toronto M5S 1A4, Canada.
Abstract:
Green policies currently incentivize concrete producers to replace portland cement with industrial byproducts to reduce their greenhouse gas (GHG) emissions. However, policies are based on attributional life cycle assessments (LCAs) that do not account for market constraints and consider byproducts either available burden-free to the user (cutoff approach) or partially responsible for the emissions generated in the upstream processes (allocation). The goal of this study was to investigate whether these approaches (and incentives) could lead to a mismanagement of byproducts and to suboptimal solutions in terms of regional GHG emissions. The use of ground granulated blast-furnace slag (GGBS) in Ontario was studied, and an optimization model to find the least GHG-intense way of using GGBS was developed. Results showed that producers should replace 30 to 40% of portland cement in high-strength concrete to minimize the regional GHG emissions associated with concrete. However, traditional LCA approaches do not suggest this solution and are estimated to lead to up to a 10% increase in concrete GHG emissions in Ontario. The substitution method, which assigns emissions or credits to byproducts based on emissions associated with the products they may displace, can yield decisions consistent with the regional emission optimization model. A revision of current policies is recommended to include market constraints.
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