Comparison of Ti-35Nb-7Zr-5Ta and Ti-6Al-4V hydrofluoric acid/magnesium-doped surfaces obtained by anodizing
Bárbara A Reis1, Laiza Mg Fais2, Ana L R Ribeiro2
1Department of Diagnosis and Surgery, São Paulo State University (Unesp), School of Dentistry, Araraquara, São Paulo, Brazil.
Objectives:
Development of a new generation of stable β alloy, free of aluminum or vanadium and with better biological and mechanical compatibility and evaluate the surface properties of Ti-6Al-4V and Ti-35Nb-7Zr-5Ta after anodization in hydrofluoric acid, followed by deposition of different electrolyte concentrations of magnesium particles by micro arc-oxidation treatment.
Methods:
Disks were anodized in hydrofluoric acid. After this first anodization, the specimens received the deposition of magnesium using different concentration (8.5% and 12.5%) and times (30s and 60s). The surface morphology was assessed using scanning electron microscopy, and the chemical composition was assessed using energy dispersive x ray spectroscopy. The surface free energy was measured from the contact angle, and the mean roughness was measured using a digital profilometer.
Results:
Anodization in hydrofluoric acid provided the formation of nanotubes in both alloys, and the best concentration of magnesium considered was 8.5%, as it was the condition where the magnesium was incorporated without covering the morphology of the nanotubes. X-ray dispersive energy spectroscopy showed magnesium incorporation in all conditions. The average roughness was increased in the Ti-35Nb-7Zr-5Ta alloy.
Conclusions:
It was concluded that anodizing could be used to deposit magnesium on the surfaces of Ti-6Al-4V and Ti-35Nb-7Zr-5Ta nanotubes, with better results obtained in samples with magnesium concentration in 8.5% and the process favored the roughness in the Ti-35Nb-7Zr-5Ta group.
