Spherical Bi₂WO₆/Bi₂S₃/MoS₂ n-p Heterojunction with Excellent Visible-Light Photocatalytic Reduction Cr(VI) Activity

Exploiting excellent photocatalytic activity and stable heterostructure composites are of critical importance for environmental sustainability. The spherical Bi₂WO₆/Bi₂S₃/MoS₂ n-p heterojunction is first prepared via an in situ hydrothermal method using Bi₂WO₆, Na₂MoO₄·2H₂O, and CH₄N₂S, in which the intermediate phase Bi₂S₃ is formed due to chemical coupling interaction of Bi₂WO₆ and CH₄N₂S. Scanning electron microscopy indicates that the compactness of the sample can be easily adjusted by changing the contents of S and Mo sources in the solution. The results of ultraviolet-visible (UV-vis) diffuse reflectance spectra, photoluminescence, transient photocurrent response, and electrochemical impedance spectra indicate that the formation of heterojunctions contributes to enhancing visible-light utilization and promoting photogenerated carrier separation and transfer. The composite material is used as a catalyst for the visible light photocatalytic reduction of Cr(VI). Remarkably, the optimal Bi₂WO₆/Bi₂S₃/MoS₂ n-p heterojunction achieves the greatest Cr(VI) reduction rate of 100% within 75 min (λ > 420 nm, pH = 2); this rate is considerably better than the Cr(VI) reduction rate of pure Bi₂WO₆. The recycling experiment also reveals that the photocatalytic performance of the n-p heterojunction toward Cr(VI) is still maintained at 80% after three cycles, indicating that the n-p heterojunction has excellent structural stability. The capture experiment proves that the main active species in the system are electrons. The reasonable mechanism of Bi₂WO₆/Bi₂S₃/MoS₂ photocatalytic reduction Cr(VI) is proposed. Our work provides new research ideas for the design of ternary heterojunction composites and new strategies for the development of photocatalysts for wastewater treatment.