Defect-modified reduced graphitic carbon nitride (RCN) enhanced oxidation performance for photocatalytic degradation...

Hydroxyl radicals (OH) have robust non-selective oxidizing properties to effectively degrade organic pollutants. However, graphitic carbon nitride (g-C₃N₄) is restricted to directly generate OH due to its intrinsic valence band. In this study, we report a facile environmental-friendly self-modification strategy to synthesize reduced graphitic carbon nitride (RCN), with nitrogen vacancies and CN functional groups. The incorporation of CN enabled to downshift the valence band level, which endowed RCN with the capacity to directly generate OH via h⁺. Experimental and instrumental analyses revealed the critical roles of nitrogen vacancies and CN groups in the modification of the RCN band structure to improve its visible light absorption and oxidizing capacity. With these superior properties, the RCN was significantly enhanced for the photocatalytic degradation of DCF under visible light irradiation. The self-modification strategy articulated in this study has strong potential for the creation of customized g-C₃N₄ band structures with enhanced oxidation performance.