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Updated: Dec 8, 2025

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Published on: August 17, 2018
Organic synthesis of fixed CO2 using nitrogen as a nucleophilic center
Ting-Kai Xiong1, Xue-Jun Li, Min Zhang
1School of Life and Environmental Sciences, Guilin University of Electronic Technology, Guilin, Guangxi 541004, People's Republic of China. zhangmin@guet.edu.cn liangyi0774@guet.edu.cn.
Abstract:
In this review, recent progress in the application of CO2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO2 and nitrogen are classified as metal catalysis, metal-free catalysis, photocatalysis and electrocatalysis. Various catalytic conditions have been used to solve the problems of thermodynamic properties and stability of CO2. The transformation mechanisms of these reactions are discussed.
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