Oxidation of Ammonia with Molecular Complexes
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Updated: Dec 7, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Peter L Dunn1, Brian J Cook1, Samantha I Johnson1
1Center for Molecular Electrocatalysis, Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
Abstract:
Oxidation of ammonia by molecular complexes is a burgeoning area of research, with critical scientific challenges that must be addressed. A fundamental understanding of individual reaction steps is needed, particularly for cleavage of N-H bonds and formation of N-N bonds. This Perspective evaluates the challenges of designing molecular catalysts for oxidation of ammonia and highlights recent key contributions to realizing the goals of viable energy storage and retrieval based on the N-H bonds of ammonia in a carbon-free energy cycle.
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