Enhanced kinetics and super selectivity toward Cs⁺ in multicomponent aqueous solutions: A robust Prussian blue...

Developing effective adsorbents for ¹³⁷Cs removal from complex wastewater systems has been a significant challenge. Although existing spheres adsorbents could improve the post-separation ability and practical operability, the adsorption kinetics are still significantly retarded due to the large intra-particle diffusion resistance. Here, we demonstrate the efficiency of a robust Prussian blue analogue/polyvinyl chloride composite membrane (PPM), which was easily prepared by a simple solvent evaporation method. In virtue of the less dense layer and ion-sieving functionality, it showed enhanced kinetics (5 h) and super selectivity (S_F = 248.3-5388.6) towards Cs⁺. New PPM was robust within a wide pH range (2-10) and exhibited favorable removal capacity (152.8 mg/g), placing it at an outstanding material for Cs⁺ removal among other adsorbents. Moreover, PPM could be simply eluted and reused using a KCl solution as eluent. A study of the adsorption mechanism confirmed an ion-exchange action during the removal process. Thus, PPM is considered to be a promising candidate for the removal of Cs⁺ from multicomponent aqueous solutions.