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Published on: June 3, 2018
A photoelectrochemical aptasensor for sensitively monitoring chloramphenicol using plasmon-driven AgNP/BiOCl
Li Xu1, Xiaoyang He, Jintao Dong
1Institute for Energy Research, School of Chemistry and Chemical Engineering, Key Laboratory of Zhenjiang, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, P. R. China. lhn@ujs.edu.cn.
Abstract:
A photoelectrochemical (PEC) aptasensor based on silver nanoparticle/BiOCl (AgNP/BiOCl) composites was constructed for detecting chloramphenicol (CAP). The surface-plasmon resonance (SPR) effect of AgNPs can focus the incident light and promote the migration and separation of the photogenerated carriers of AgNP/BiOCl composites. As a result, the AgNP/BiOCl composites showed an enhanced PEC performance compared to that of pure BiOCl. A PEC CAP aptasensor was fabricated using AgNP/BiOCl composites as photoactive materials and a CAP aptamer as a recognition element. The PEC aptasensor exhibited a broad linear response range (0.2 pM-10 nM), a low limit of determination (0.08 pM), satisfactory selectivity, stability, and reproducibility to meet the practical analysis requirements. This work demonstrates that the PEC CAP aptasensor has a promising prospect in environmental assays.

