Random alloy and intermetallic nanocatalysts in fuel cell reactions

Fuel cells that use small organic molecules or hydrogen as the anode fuel can power clean electric vehicles. From an experimental perspective, the possible fuel cells' electrocatalytic reaction mechanisms are obtained through in situ electrochemical spectroscopy techniques and density functional theory calculations, providing theoretical guidance for further development of novel nanocatalysts. As advanced nanocatalysts for fuel cells' electrochemical reactions, alloy nanomaterials have greatly improved electrocatalytic activity and stability and have attracted widespread attention. Enhanced electrocatalytic performance of alloy nanocatalysts could be closely related to the synergistic effects, such as electronic and strain effects. Depending on the arrangement of atoms, alloys can be classified into random alloy and intermetallic compounds (ordered structure). Intermetallic compounds generally have lower heats of formation and stronger heteroatomic bonding strength relative to the random alloy, resulting in high chemical and structural stability in either full pH solutions or electrochemical tests. Here, we summarize the latest advances and the structure-function relationship of noble metal alloy nanocatalysts, among which Pt-based catalysts are the main ones, as well as comprehensively understand why they significantly affect the electrocatalytic performance of fuel cells. Novel alloy nanocatalysts with a robust three-phase interface to achieve efficient charge and mass transfer can obtain desirable activity and stability in the electrochemical workstation tests, and is expected to acquire a higher power density on fuel cell test systems with harsh test conditions.