Lignocellulose, Cellulose and Lignin as Renewable Alternative Fuels for Direct Biomass Fuel Cells

In recent years the use of renewable sources, such as lignocellulosic biomass (LCB), as the fuel for various types of fuel cells received growing interest. Different types of fuel cells, that is, operated at low temperatures (T<100 °C; microbial fuel cells (MFC), alkaline (AFCs) and flow fuel cells (FFCs)), intermediate temperatures (T in the range 150-300 °C, proton-conducting inorganic-organic composite membrane fuel cells), and high temperatures (T≥500 °C, direct carbon fuel cells (DCFCs)), have been used for the conversion of the chemical energy in LCB to electrical energy. The economic advantage of the direct use of LCB consists of avoiding the acid hydrolysis of cellulose to glucose for low-temperature fuel cells and the pretreatment at high temperatures necessary to convert biomass to biochar (pyrolysis) in the case of high-temperature fuel cells. In this Review, the characteristics of direct biomass fuel cells are presented and their performance is compared with that of indirect biomass fuel cells fed with glucose (low-temperature fuel cells) and biochar (high-temperature fuel cells).