Related Experiment Video
Updated: Dec 7, 2025
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Spotlight on Photoinduced Aryl Migration Reactions
Marie Huynh1, Maxime De Abreu1, Philippe Belmont1
1UMR CNRS 8038 CiTCoM, Université de Paris, 4 avenue de l'Observatoire, 75006, Paris, France.
Abstract:
Rearrangement reactions are certainly one of the most useful approaches towards complex structures in organic chemistry. With efficient conditions, it is indeed possible to convert simple substrates into highly functionalized products. Moreover, combining this approach with an attractive initiation process, such as visible-light catalysis, makes these reactions particularly powerful. Recently, tremendous improvements have been made, owing to a better understanding of photoredox mechanisms. In this review, recent progress on visible-light aryl migration reactions is discussed, focusing especially on Smiles rearrangement and related reactions.
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