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Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes
Shohei Koyama1, Tappei Tanabe, Shinya Takaishi
1Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan. h-iguchi@tohoku.ac.jp.
Chemical Communications (Cambridge, England)
|October 1, 2020
Abstract:
Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(ii) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction.
