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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

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Published on: March 20, 2014

Bottleable NiCl₂(dppe) as a catalyst for the Markovnikov-selective hydroboration of styrenes with

Toru Hashimoto¹, Toshiya Ishimaru¹, Keisuke Shiota¹

¹Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan. hashimoto-toru-kh@ynu.ac.jp yamaguchi-yoshitaka-hw@ynu.ac.jp.

Chemical Communications (Cambridge, England)

|October 1, 2020

Abstract:

Although transition-metal-catalysed hydroboration reactions of alkenes have been extensively studied, only three examples using Ni complexes have been reported so far. In this study, we have examined hydroboration reactions of alkenes using Ni/phosphine complexes. The commercially available and bottleable complex NiCl2(dppe) (dppe = 1,2-bis(diphenylphosphino)ethane) serves as a catalyst for the highly Markovnikov-selective hydroboration of styrene derivatives that affords the desired Markovnikov products in high yield.

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