EDTAD-modified cassava stalks loaded with Fe₃O₄: highly efficient removal of Pb²⁺ and Zn²⁺ from aqueous solution

In this study, a novel magnetic cassava stalk composite (M-EMCS) was prepared through modification with ethylenediamine tetraacetic anhydride (EDTAD) and loading of Fe₃O₄. The surface morphology, molecular structure, and magnetic characteristics of the composite were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), vibrating-sample magnetometer (VSM), and X-ray diffraction (XRD). It was shown that EDTAD and Fe₃O₄ were successfully modified and loaded in cassava straw (CS), respectively. The capacity of M-EMCS to absorb heavy metals under different influencing factors was tested by atomic absorption spectroscopy. The adsorption processes of both Pb²⁺ and Zn²⁺ were suitably described by second-order kinetic models and Langmuir models, indicating monolayer chemisorption. M-EMCS had high adsorption rates and adsorption capacities for these two metal ions. The adsorption of Pb²⁺ and Zn²⁺ reached a plateau after 10 min, and the adsorption capacity of Pb²⁺ (163.93 mg/g) was higher than that of Zn²⁺ (84.74 mg/g). Thermodynamic analysis showed that the adsorption of two metals by M-EMCS was spontaneous, endothermic, and irreversible. XPS analysis showed that M-EMCS mainly removes Pb²⁺ and Zn²⁺ through ion exchange, chelation, and redox. Graphical abstract.