Effect of multi-walled carbon nanotubes on extractability of Sb and Cd in contaminated soil

The interaction between multi-walled carbon nanotubes (MWCNTs) and soil heavy metals was rarely studied. With the convenience of detecting multiple metal elements by ICP-AES, this paper examined the potential effectiveness of MWCNTs on extractability of antimony (Sb) and cadmium (Cd) in contaminated soil. Three-step sequential extraction procedure, toxicity characteristic leaching procedure, bioaccessibility and CaCl₂ single extraction were employed to evaluate Sb and Cd speciations and their extractabilities. According to our results, only at low Sb content level of 100 mg/kg, antimony bioavailability reduced with MWCNTs addition of 0.3% and 0.9% by 22.97% and 20.74%, respectively, which might due to the increase of adsorption point, nevertheless, the excess Sb(OH)₆^- was not adsorbed more efficiently. Secondly, due to the difference in effective specific surface area, only under the condition of high content level and MWCNTs addition of 0.1%, the mild acid-soluble fraction increased at most by 15.40% for Sb and 9.40% for Cd, respectively. However, in terms of TCLP-extractable Sb and Cd and CaCl₂-extractable Sb and Cd, no significant, continuous, regular extractability pattern were found. Overall, MWCNTs were selective on extractability of soil heavy metals due to mechanisms of physical adsorption. This paper provides data reference for the interaction between MWCNTs and soil heavy metals extractability.