Electrochemical regeneration of spent activated carbon from drinking water treatment plant at different scale...

The electrochemical regeneration of real spent activated carbons (AC) used in drinking water treatment plants was studied at different reactor scales. The electrochemical regeneration was carried out in a 6 g filter-press cell and a 3.5 kg batch reactor, allowing the scaling-up of the process between the two electrolytic reactors. The effect of the electrolyte, the divided/undivided compartment configuration and the current density were studied in the filter-press cell. The effect of compartment configuration and the influence of the regeneration time were studied in the scaled-up reactor. A current density of 0.025 A cm^-2 was used and the electrodes were Pt/Ti as anode and Pt/Ti and stainless-steel as cathode. The ACs were characterized by N₂ adsorption isotherms to analyse the recovery of porosity and TPD-MS to analyse the AC surface after the electrochemical treatment. In filter-press cell, a recovery of the surface area of 96% was achieved after 8 h of treatment, by introducing the AC in the cathodic compartment using 0.05 M H₂SO₄ solution as electrolyte. In the 3.5 kg electrochemical reactor, 95% of the pristine AC surface area was recovered. Thus, electrochemical methods can provide a green alternative to the regeneration of spent AC.