Novel Strategy for Fabricating Multilayer Porous Membranes with Varying Porosity

CO₂-assisted polymer compression (CAPC) is a method for fabricating porous polymer materials in which the polymer is plasticized with CO₂ and then pressed. In this work, a two-step molding method is adapted, and a porous membrane with multiple layers of varying porosity is fabricated by laminating sheets of a single starting material. A model is constructed in which the expansion owing to CO₂ and compression reflected by the longitudinal elastic modulus are considered. The model is constructed based on a two-layer experiment and extended to three layers. From the model simulation, the conditions for fabricating a multilayer porous polymer membrane with three layers of varying porosity (0.6, 0.5, and 0.4) and identical thickness (0.6 mm) are calculated. Finally, a porous membrane with varying porosity is fabricated based on the simulated design.