Use of multiple isotopes to evaluate nitrate dynamics in groundwater under the barrier effect of underground cutoff...

Underground cutoff walls are useful in conserving groundwater and preventing seawater intrusion in coastal regions. However, the environmental effects of human activities on groundwater quality in the upstream area of the underground cutoff wall over the long term are not clear. In this study, combined analysis of multiple isotopes (δ¹⁵N-NO₃^-, δ¹⁸O-NO₃^-, δ²H, and δ¹⁸O-H₂O) and nitrate concentrations was used to assess the effect of underground cutoff walls on nitrogen dynamics in groundwater in an agricultural area in China. We sampled groundwater wells in the upstream and downstream areas of the underground walls in April, July, and September. The results indicated that the underground cutoff walls hampered the horizontal groundwater flow, making the upstream groundwater a closed system, which led to an increase in the nitrate concentration and accelerated nitrification processes. Manure was the main nitrate source in the upstream groundwater, and its levels in the groundwater were similar during the three seasons, indicating that there was no difference in the nitrate sources in the upstream groundwater among the three seasons. Hence, further management measures for manure application may be critical for groundwater protection in the upstream area of underground cutoff walls.