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Related Concept Videos

Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Lignin-Based Solid Polymer Electrolytes: Lignin-Graft-Poly(ethylene glycol).

Hailing Liu1, Logan Mulderrig1,2, Daniel Hallinan1,2

  • 1Department of Chemical and Biomedical Engineering, Florida A&M University-Florida State University College of Engineering, 2525 Pottsdamer Street, Suite A131, Tallahassee, FL, 32310, USA.

Macromolecular Rapid Communications
|October 8, 2020
PubMed
Summary

This study introduces lignin-graft-poly(ethylene glycol) (PEG) as a novel solid electrolyte material. The new polymer electrolytes show enhanced ionic conductivity at ambient temperatures, paving the way for sustainable energy storage applications.

Keywords:
batteriesbiomassligninpoly(ethylene glycol)solid polymer electrolytes

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Electrochemistry

Background:

  • Lignin, an abundant and sustainable aromatic polymer, is underutilized in solid electrolytes due to synthesis challenges.
  • Developing novel polymer electrolytes is crucial for advancing energy storage technologies.

Purpose of the Study:

  • To synthesize and characterize lignin-graft-poly(ethylene glycol) (PEG) for solid electrolyte applications.
  • To evaluate the ionic conductivity of these novel lignin-based polymer electrolytes.

Main Methods:

  • Functionalization of natural lignin's hydroxyl groups to alkenes.
  • Graft-copolymerization of PEG thiol onto lignin via photoredox thiol-ene reaction.
  • Preparation and conductivity testing of polymer electrolytes with lithium bis-trifluoromethanesulfonimide.

Main Results:

  • Two lignin-graft-PEG copolymers with varying lignin content (22 wt% and 34 wt%) were successfully synthesized.
  • The polymer graft electrolytes achieved ionic conductivity up to 1.4 × 10-4 S cm-1 at 35 °C.
  • Lignin incorporation resulted in significantly higher ionic conductivity at ambient temperature compared to pure PEG.

Conclusions:

  • Lignin-graft-PEG is a promising material for solid polymer electrolytes.
  • The developed materials offer enhanced ionic conductivity, particularly at room temperature.
  • This work demonstrates a viable route for incorporating sustainable lignin into advanced energy storage materials.