Trace element mass fractions in road dust as a function of distance from road

Road dust particles play an important role in atmospheric pollution and are associated with adverse human health effects. Traffic emissions are a major source of particles in road dust. However, there has been limited information about the relationship between distance from road and traffic-related elements levels in road dust. We investigated the relationships between proximity to the nearest major roadway and trace element mass fractions in PM₁₀ and PM_2.5 re-suspended from the road surface, based on measurements at three different distance ranges. We found that mass fractions of Ba, Cu, Zr, Zn, Cl, Co, Cr, Ca, Ti in PM₁₀ road dust as well as Zr, Cu, Cl, Zn, Cr, Ti, Mn, Ca, Ni, and Fe in PM_2.5 road dust, significantly decreased with distance from major road. Most of these elements are associated with road traffic emissions, including both tailpipe and non-tailpipe emissions. The decrease rates differed among elements due to differences in local traffic contributions. The decreases for elements which are mainly associated with non-tailpipe traffic emissions (e.g., Ba, Zr) were more dramatic. Our results indicate that traffic emissions, especially non-tailpipe emissions, contribute substantially to road dust, suggesting the need for control strategies for non-tailpipe emissions. Implications: We investigated the relationships between road proximity with trace element mass fractions in PM10 and PM2.5 re-suspended from the road surface. We observed significant decrease of traffic-related elements in PM10 and PM2.5 road dust with log distance from major road. We also found that the mass fractions for elements, which mainly come from traffic decrease more sharply compared to elements which come from both traffic and other sources. Our results indicate that traffic emissions contribute substantially to road dust, and imply that the distance to major road can be used as a proxy for ambient exposure.