Tunable bandgap and isotropic light absorption from bismuth-containing GaAs core-shell and multi-shell nanowires

Semiconductor core-shell nanowires based on the GaAs substrate are the building blocks of many photonic, photovoltaic and electronic devices, thanks to their associated direct bandgap and highly tunable optoelectronic properties. The selection of a suitable material system is crucial for custom designed nanowires tailored for optimised device performance. Bismuth-containing GaAs materials are an imminent class of semiconductors which not only enable an exquisite control over the alloy strain and electronic structure but also offer the possibility to suppress internal loss mechanisms in photonic devices. Whilst the experimental efforts to incorporate GaBixAs1-x alloys in the nanowire active region are still at an early stage, the theoretical understanding of the optoelectronic properties of such nanowires is only rudimentary. This work elucidates and quantifies the role of nanowire physical attributes such as its geometry parameters and bismuth incorporation in designing light absorption wavelength and polarisation response. Based on the multi-million atom tight-binding simulations of the GaBixAs1-x/GaAs core-shell and GaAs/GaBixAs1-x/GaAs multi-shell nanowires, our results predict a large tuning of the absorption wavelength, ranging from 0.9 μm to 1.6 μm, which can be controlled by engineering either Bi composition or nanowire diameter. The analysis of their strain profiles indicates a tensile character leading to significant light-hole mixing in the valence band states. This offers a possibility to achieve polarisation-insensitive light interaction, which is desirable for several photonic devices involving amplification and modulation of light. Furthermore, at low Bi compositions, the carrier confinement is quasi type-II, which further broadens the suitability of these nanowires for a myriad of applications requiring large carrier separations. The presented results provide a systematic and comprehensive understanding of the GaBixAs1-x nanowire properties and highlight new possibilities for future technologies in photonics, quantum optics and solar energy harvesting.