Evaluation of silver nanoparticles (AgNPs) penetration through a clay liner in landfills

Most products containing engineered nanomaterials are disposed at landfills in the final stage of their lifecycle. This study aims to assess landfill liners as a final barrier of disposed silver nanoparticles (AgNPs). Sorption and transport of AgNPs were investigated in the laboratory-scale simulation of landfill liner conditions. Field soil (silt loam) and bentonite were tested in batch sorption experiments respectively. To test transportation, 3 cm thick mixture of the field soil and the bentonite constituted the porous media to meet the criteria for compacted clay liner of landfill. Mathematical modeling in the experimental and actual landfill conditions was also conducted. The results demonstrated considerable extent of sorption by both types of sorbents. The breakthrough of AgNPs was not observed for 200 days (over 20 pore volume). In general, the experimental results indicated that AgNPs cannot easily pass through the landfill clay liner under present standards. Modeling results also showed that AgNPs could be blocked effectively. Although long-term tests are still required, these results clearly show resistance to current sanitary landfill liners against AgNP penetration. As the trial to assess the safety of landfills against AgNP migration, this work provides insights into the fate and transport of nanomaterials in the landfill environment.