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Updated: Dec 5, 2025

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
Particles confined in arbitrary potentials with a class of finite-range repulsive interactions
Avanish Kumar1, Manas Kulkarni1, Anupam Kundu1
1International Centre for Theoretical Sciences, Tata Institute of Fundamental Research, Bengaluru 560089, India.
Abstract:
In this paper, we develop a large N field theory for a system of N classical particles in one dimension at thermal equilibrium. The particles are confined by an arbitrary external potential, V_{ex}(x), and repel each other via a class of pairwise interaction potentials V_{int}(r) (where r is distance between a pair of particles) such that V_{int}∼|r|^{-k} when r→0. We consider the case where every particle is interacting with d (finite-range parameter) number of particles to its left and right. Due to the intricate interplay between external confinement, pairwise repulsion, and entropy, the density exhibits markedly distinct behavior in three regimes k>0, k→0, and k<0. From this field theory, we compute analytically the average density profile for large N in these regimes. We show that the contribution from interaction dominates the collective behavior for k>0 and the entropy contribution dominates for k<0, and both contribute equivalently in the k→0 limit (finite-range log-gas). Given the fact that this family of systems is of broad relevance, our analytical findings are of paramount importance. These results are in excellent agreement with brute-force Monte Carlo simulations.
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