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Updated: Dec 4, 2025

Scanning-probe Single-electron Capacitance Spectroscopy
Published on: July 30, 2013
Electroosmosis as a probe for electrostatic correlations
Ivan Palaia1, Igor M Telles2, Alexandre P Dos Santos2
1Department of Physics and Astronomy, Institute for the Physics of Living Systems, University College London, London WC1E 6BT, UK and MRC Laboratory for Molecular Cell Biology, University College London, London WC1E 6BT, UK.
Abstract:
We study the role of ionic correlations on the electroosmotic flow in planar double-slit channels, without salt. We propose an analytical theory, based on recent advances in the understanding of correlated systems. We compare the theory with mean-field results and validate it by means of dissipative particle dynamics simulations. Interestingly, for some surface separations, correlated systems exhibit a larger flow than predicted by mean-field. We conclude that the electroosmotic properties of a charged system can be used, in general, to infer and weight the importance of electrostatic correlations therein.
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