Nb₂O₅ nanoparticles decorated with magnetic ferrites for wastewater photocatalytic remediation

Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (Nb₂O₅) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFe₂O₄) or magnesium ferrite (MgFe₂O₄)) for atrazine photodegradation. Thus, the decorated Nb₂O₅ was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFe₂O₄ (53 emu g^-1) and MgFe₂O₄ (19 emu g^-1) nanoparticles, promoting the magnetic removal of Nb₂O₅:CoFe₂O₄ and Nb₂O₅:MgFe₂O₄ nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic Nb₂O₅-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic Nb₂O₅ nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes.