Phosphonic acid: a long-standing and versatile crop protectant

Phosphonic acid-based fungicides, also referred to as phosphonates, have been used extensively as crop protectants in horticulture since the late 1970s, and more recently in native ecosystems and forestry. Discovering that phosphonates are effective against foliar and soilborne oomycete diseases, such as those caused by species of Phytophthora, Pythium and Plasmopara, was a significant breakthrough, especially for soilborne pathogens that are notoriously difficult to manage. Phosphonates have played an important role in protection of forests and sensitive natural ecosystems, under threat from these pathogens. Since introduction, their increased application in management of non-oomycete diseases, along with other functionalities, demonstrates their versatility in agriculture and more broadly. Continued use of phosphonic acid crop protectants will be underpinned by demonstrated efficacy and safety, and a better understanding of specific interactions within the plant, pathogen and environment. © 2020 Society of Chemical Industry.