Glycine-Functionalized CsPbBr₃ Nanocrystals for Efficient Visible-Light Photocatalysis of CO₂ Reduction

Capping ligands are indispensable for the preparation of metal-halide-perovskite (MHP) nanocrystals (NCs) with good stability; however, the long alkyl-chain capping ligands in conventional MHP NCs will be unfavorable for CO₂ adsorption and hinder the efficient carrier separation on the surface of MHP NCs, leading to inferior catalytic activity in artificial photosynthesis. Herein, CsPbBr₃ nanocrystals with short-chain glycine as ligand are constructed through a facile ligand-exchange strategy. Owing to the reduced hindrance of glycine and the presence of the amine group in glycine, the photogenerated carrier separation and CO₂ uptake capacity are noticeably improved without compromising the stability of the MHP NCs. The CsPbBr₃ nanocrystals with glycine ligands exhibit a significantly increased yield of 27.7 μmol g^-1  h^-1 for photocatalytic CO₂ -to-CO conversion without any organic sacrificial reagents, which is over five times higher than that of control CsPbBr₃ NCs with conventional long alkyl-chain capping ligands.