Au Nanoparticles Decorated Mesoporous SiO₂ -WO₃ Hybrid Materials with Improved Pore Connectivity for Ultratrace...

Semiconducting metal oxides-based gas sensors with the capability to detect trace gases at low operating temperatures are highly desired in applications such as wearable devices, trace pollutant detection, and exhaled breath analysis, but it still remains a great challenge to realize this goal. Herein, a multi-component co-assembly method in combination with pore engineering strategy is proposed. By using bi-functional (3-mercaptopropyl) trimethoxysilane (MPTMS) that can co-hydrolyze with transition metal salt and meanwhile coordinate with gold precursor during their co-assembly with PEO-b-PS copolymers, ordered mesoporous SiO₂ -WO₃ composites with highly dispersed Au nanoparticles of 5 nm (mesoporous SiO₂ -WO₃ /Au) are straightforward synthesized. This multi-component co-assembly process avoids the aggregation of Au nanoparticles and pore blocking in conventional post-loading method. Furthermore, through controlled etching treatment, a small portion of silica can be removed from the pore wall, resulting in mesoporous SiO₂ -WO₃ /Au with increased specific surface area (129 m²  g^-1 ), significantly improved pore connectivity, and enlarged pore window (>4.3 nm). Thanks to the presence of well-confined Au nanoparticles and ε-WO₃ , the mesoporous SiO₂ -WO₃ /Au based gas sensors exhibit excellent sensing performance toward ethanol with high sensitivity (R_a /R_g = 2-14 to 50-250 ppb) at low operating temperature (150 °C).