Related Experiment Video
Updated: Dec 3, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure of melaminium cyano-acetate monohydrate
Bhawani Sigdel Regmi1, Allen Apblett2, Douglas Powell3
1Department of Chemistry and Biochemistry, University of North Georgia, Oakwood, Georgia, USA.
Abstract:
The asymmetric unit of the title compound, 2,4,6-tri-amino-1,3,5-triazin-1-ium cyano-acetate monohydrate, C3H7N6 +·NCCH2COO-·H2O, consists of a melaminium cation, a cyano-acetate anion and a water mol-ecule, which are connected to each other via N-H⋯O and O-H⋯O hydrogen bonds, generating an eight-membered ring. In the crystal, the melaminium cations are connected by two pairs of N-H⋯N hydrogen bonds, forming tapes along [110]. These tapes develop a three-dimensional network through N-H⋯O, O-H⋯O, N-H⋯N and C-H⋯O hydrogen bonds between the cations, anions and water mol-ecules.
More Related Videos
Related Concept Videos
Structure of Amines
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Structures of Carboxylic Acid Derivatives
Carboxylic acid derivatives contain an acyl group attached to a heteroatom such as chlorine, oxygen, or nitrogen. The carbonyl carbon and oxygen are both sp2-hybridized with an unhybridized p orbital.
The three sp2 orbitals of the carbonyl carbon form three σ bonds, one each with the carbonyl oxygen, the α carbon, and the heteroatom, whereas the other two sp2 orbitals of the carbonyl oxygen are occupied by the lone pairs. Further, the unhybridized p...
Nomenclature of Carboxylic Acid Derivatives: Amides and Nitriles
The IUPAC and common names of amides are derived from the parent carboxylic acid, by replacing the suffix “oic acid” and “ic acid,” respectively, with “amide.” In the following example, the IUPAC name ethanamide is derived from ethanoic acid, and the common name, acetamide, is obtained from acetic acid.
Structures of Solids
Aldehydes and Ketones with HCN: Cyanohydrin Formation Overview

