Covalent Triazine Frameworks Obtained from Nitrile Monomers for Sustainable CO₂ Catalysis

Carbon dioxide catalytic conversion (i. e., CO₂ catalysis) is considered as one of the most promising technologies to control CO₂ emissions, which is of great significance to build a sustainable society with green low-carbon cycle. In view of its thermodynamic stability and kinetic inertness, CO₂ selective activation is still desired. Nowadays, the traditional strategy is to selectively capture and efficiently convert atmospheric CO₂ into high value-added chemicals and fuels. Covalent triazine frameworks (CTFs) as a newly emerging and attractive kind of porous organic polymer (POP) have drawn worldwide attention among heterogeneous catalysis because of their nitrogen-rich porous structures and exceptional physicochemical stabilities. In this Minireview, the focus was mainly placed on the structural design and synthesis of CTFs and their applications in CO₂ catalysis including CO₂ cycloaddition, CO₂ carboxylation, CO₂ hydrogenation, CO₂ photoreduction, and CO₂ electroreduction. By discussing the structure-property relationship, valuable guidance from a sustainable perspective may be provided for developing precisely designed CTFs with high performance and excellent industrial application prospects in sustainable CO₂ catalysis.