Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Ionic Crystal Structures02:42

Ionic Crystal Structures

16.4K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.4K
Metallic Solids02:37

Metallic Solids

20.1K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
20.1K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

19.4K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
19.4K
Structures of Solids02:22

Structures of Solids

17.0K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
17.0K
Predicting Molecular Geometry02:27

Predicting Molecular Geometry

42.9K
VSEPR Theory for Determination of Electron Pair Geometries
42.9K
Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

84.9K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
84.9K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Alkane Coordination by a Neutral, Lewis Acidic Magnesium Complex.

Journal of the American Chemical Society·2025
Same author

Isolated and Condensed Ru(In/Sn)<sub>6</sub> Octahedra Clustering Together: A Mixed Valence Phase of Ru<sub>4</sub>Sn<sub>20</sub>In<sub>2</sub>O<sub>21</sub> with Ru<sup>0</sup>, Ru<sup>+</sup>, and Ru<sup>2+</sup> Species.

Inorganic chemistry·2025
Same author

New structural insights into Fe<sub>2</sub>P<sub>2</sub>O<sub>7</sub> - unravelling an unresolved dispute and three reversible phase transitions.

IUCrJ·2025
Same author

An Operationally Unsaturated Iridium-Pincer Complex That C-H Activates Methane and Ethane in the Crystalline Solid-State.

Journal of the American Chemical Society·2025
Same author

Manipulating a Thermosalient Crystal Using Selective Deuteration.

Journal of the American Chemical Society·2025
Same author

K<sub>0.72</sub>Na<sub>1.71</sub>Ca<sub>5.79</sub>Si<sub>6</sub>O<sub>19</sub> - the first oligosilicate based on [Si<sub>6</sub>O<sub>19</sub>]-hexamers and its stability compared to cyclosilicates.

Acta crystallographica Section B, Structural science, crystal engineering and materials·2024
Same journal

Photoinduced Charge-Transfer Suppresses Triplet Formation Efficiency in Thiocoumarins: Evidence from Ultrafast Spectroscopy and Theoretical Calculations.

The journal of physical chemistry. A·2026
Same journal

Porphyrin Aggregation Revisited: From the Four-Orbital Gouterman Model to an Eight-Orbital Framework in Porphin H-Dimers.

The journal of physical chemistry. A·2026
Same journal

Unraveling the Electronic Origin of Selectivity in Ambimodal Transition States with Valence Bond Theory.

The journal of physical chemistry. A·2026
Same journal

Mechanism and Kinetics of the Initial Oxidative Ring-Opening of Corannulene Radicals under Combustion Conditions.

The journal of physical chemistry. A·2026
Same journal

High-Resolution Absorption Spectroscopy of ND<sub>3</sub> between 59,000 and 93,000 cm<sup>-1</sup>.

The journal of physical chemistry. A·2026
Same journal

Twisted-Driven Photoionization of Aligned Chiral Molecules: Signatures of Circular and Helical Dichroism.

The journal of physical chemistry. A·2026
See all related articles

Related Experiment Video

Updated: Dec 3, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.4K

A Discrete Chloride Monohydrate: A Solid-State Structural and Spectroscopic Characterization.

Mohammed S Abdelbassit1, Owen J Curnow1, Eugen Libowitzky2

  • 1School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand.

The Journal of Physical Chemistry. A
|October 29, 2020
PubMed
Summary
This summary is machine-generated.

Researchers report the first solid-state structure of a discrete chloride monohydrate ion, [Cl(H2O)]-. This finding advances understanding of hydrogen bonding in crystalline solids.

More Related Videos

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

8.4K
Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
10:28

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

9.3K

Related Experiment Videos

Last Updated: Dec 3, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.4K
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

8.4K
Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
10:28

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy

Published on: May 27, 2018

9.3K

Area of Science:

  • Solid-state chemistry
  • Inorganic chemistry
  • Crystallography

Background:

  • Discrete anionic species in solid-state structures are fundamental to understanding chemical bonding.
  • Characterizing novel molecular and ionic species provides insights into chemical interactions.

Purpose of the Study:

  • To report the first solid-state structure of a discrete chloride monohydrate species, [Cl(H2O)]-.
  • To characterize its vibrational properties using various spectroscopic techniques.

Main Methods:

  • Isolation of the target species as a salt with the tris(dipropylamino)cyclopropenium cation.
  • Structural characterization using X-ray and neutron diffraction.
  • Vibrational analysis via Infrared (IR), far-infrared, and Raman spectroscopy.

Main Results:

  • The solid-state structure of the [Cl(H2O)]- anion was successfully determined for the first time.
  • Spectroscopic studies confirmed the presence and interactions within the monohydrate species.
  • Investigation of D2O and HDO isotopomers provided further details on hydrogen bonding.

Conclusions:

  • The study presents a novel discrete chloride monohydrate species in the solid state.
  • Structural and spectroscopic data elucidate the nature of hydrogen bonding in this unique ion.
  • This work expands the known diversity of anionic hydrates in crystalline environments.