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Related Concept Videos

Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)01:16

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Ring-opening metathesis polymerization or ROMP involves strained cycloalkenes as starting materials. The mechanism of ROMP proceeds by reacting cycloalkene with Grubbs catalyst to give metallacyclobutane intermediate which undergoes a ring-opening reaction to form new carbene. The new carbene reacts with another molecule of cycloalkene. Repetition of these steps leads to the formation of an unsaturated open-chain polymer product. All these steps are reversible, however, relieving the ring...
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Fabrication of Polymer Microspheres for Optical Resonator and Laser Applications
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Tunable microring resonators using light-activated functional polymer coatings.

Amado M Velázquez-Benítez, Juan Hernández-Cordero

    Optics Letters
    |November 2, 2020
    PubMed
    Summary

    We developed tunable microring resonators (TMRs) using light-activated polymers on optical fibers. Visible light emission from a fluorescent layer tunes the TMRs, offering a 1.3 nm spectral shift.

    Area of Science:

    • Photonics and optical engineering
    • Materials science
    • Polymer chemistry

    Background:

    • Microring resonators (TMRs) are crucial optical devices.
    • Controlling TMR spectral features is essential for advanced applications.
    • Light-activated materials offer novel tuning mechanisms.

    Purpose of the Study:

    • To demonstrate tunable microring resonators (TMRs) using light-activated functional polymer coatings.
    • To investigate the photoinduced effects for spectral tuning.
    • To explore the potential of polymer-based composites in optical sensing and modulation.

    Main Methods:

    • Fabrication of TMRs on glass optical fibers using two polydimethylsiloxane-based layers.
    • Incorporation of an azobenzene dye and a fluorescent ytterbium and erbium-doped sodium yttrium fluoride powder.

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  • Utilizing infrared pumping to induce green up-conversion emission and trigger photoinduced birefringence.
  • Main Results:

    • Successful demonstration of tunable microring resonators (TMRs).
    • Achieved a linear shift in resonance peaks with pump power, resulting in a 1.3 nm tuning range.
    • Observed and discussed both photoinduced and photothermal effects contributing to the tuning mechanism.

    Conclusions:

    • Tunable microring resonators (TMRs) can be effectively fabricated using light-activated polymer coatings.
    • The interplay of photoluminescence and photoinduced birefringence provides a viable tuning method.
    • These findings open avenues for novel optical devices with light-controlled spectral properties.