Mixed Alkali Effect in Silicate Glass Structure: Viewpoint of ²⁹Si Nuclear Magnetic Resonance and Statistical...

The mixed alkali effect in glasses is the deviation from linear property changes when alkali cations are mixed. The extent of this effect and its structural origin remain topics of interest. In this work, we use a statistical mechanics approach to predict the composition-structure relationship in mixed modifier Na₂O-K₂O-SiO₂ glasses. This is achieved by accounting for the enthalpy between each pairwise alkali ion and silicate unit interaction. The initial enthalpy parameters are obtained based on experimental structural data for binary Na₂O-SiO₂ and K₂O-SiO₂ glasses, which can be transferred to predict the short-range order structure of mixed modifier glasses without additional free parameters. To this end, we have performed ²⁹Si magic angle spinning NMR spectroscopy measurements on y(xNa₂O-(1 - x)K₂O)-(100 - y)SiO₂ glasses with x = 0, 0.25, 0.5, 0.75, and 1 and y = 34, 42, and 50. Good agreement between experimental data and model predictions are observed. Finally, we use this information to discuss the relative entropic and enthalpic contributions to the mixed modifier effect in silicate glass structure.