Solvatochromic Photoluminescent Effects in All-Inorganic Manganese(II)-Based Perovskites by Highly Selective...

The development of lead-free perovskite photoelectric materials has been an extensive focus in the recent years. Herein, a novel one-dimensional (1D) lead-free CsMnCl₃ (H₂ O)₂ single crystal is reported with solvatochromic photoluminescence properties. Interestingly, after contact with N,N-dimethylacetamide (DMAC) or N,N-dimethylformamide (DMF), the crystal structure can transform from 1D CsMnCl₃ (H₂ O)₂ to 0D Cs₃ MnCl₅ and finally transform into 0D Cs₂ MnCl₄ (H₂ O)₂ . The solvent-induced crystal-to-crystal phase transformations are accompanied by loss and regaining of water of crystallization, leading to the change of the coordination number of Mn²⁺ . Correspondingly, the luminescence changes from red to bright green and finally back to red emission. By fabricating a test-paper containing CsMnCl₃ (H₂ O)₂ , DMAC and DMF can be detected quickly with a response time of less than one minute. These results can expand potential applications for low-dimensional lead-free perovskites.