Controlled Synthesis and Properties of 3d-4f Metals Co-doped Polyoxometalates-Based Materials

It is challenging to explore and prepare polyoxometalates-based nanomaterials (PNMs) with controllable morphologies and diversiform components. Herein, 3d-4f metals are introduced into isopolyoxometalates and Anderson-type polyoxometalates, CeCdW₁₂ nanoflower and EuCrMo₆ microflaky have been fabricated respectively. A series of control experiments are carried out to identify the impact factors on the rare morphologies in PNMs. Furthermore, upon excitation at 396 nm, the emission spectrum of EuCrMo₆ displays five prominent f - f emitting peaks at 674, 685, 690, 707, and 734 nm that are assigned to Eu^{3+ 5}D₀ → ⁷F_J (J = 0, 1, 2, 3, 4) transitions. Meanwhile, the VSM results show that the Cr⁺³ ions in EuCrMo₆ display anti-ferromagnetic interactions when the temperature is lower than - 17.54 K. After rising temperature, this material exhibits paramagnetic property. This work opens up strategies toward the brand new morphologies and components of PNMs, endowing this kind of material with new functions.