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Updated: Dec 2, 2025

Synthesis of Core-shell Lanthanide-doped Upconversion Nanocrystals for Cellular Applications
Published on: November 10, 2017
State-of-the-art and prospects for intense red radiation from core-shell InGaN/GaN nanorods
Evgenii A Evropeitsev1, Dmitrii R Kazanov2, Yoann Robin3
1Ioffe Institute, 26 Politekhnicheskaya, St Petersburg, Russia, 194021. evropeitsev@beam.ioffe.ru.
Improving red light emission in InGaN/GaN quantum well nanorods is key for white LEDs and displays. This study reveals defect luminescence masks polar quantum well emission, suggesting a hybrid design to enhance red light output.
Area of Science:
- Semiconductor physics
- Materials science
- Optoelectronics
Background:
- Core-shell nanorods (NRs) with Indium Gallium Nitride/Gallium Nitride (InGaN/GaN) quantum wells (QWs) are essential for advanced lighting and display technologies.
- A significant challenge is the weak red light emission intensity from these NRs, hindering their full potential in monolithic white light-emitting diodes (LEDs) and multi-color displays.
Purpose of the Study:
- To investigate the causes of weak red light emission in InGaN/GaN core-shell NRs.
- To identify strategies for enhancing red light output for improved device performance.
Main Methods:
- Photoluminescence measurements were conducted on various NRs under different power, temperature, and time-resolved conditions.
- Calculations of electromagnetic field distribution within the NRs were performed to understand photon state density.
- A novel hybrid nanorod design was proposed based on the experimental and theoretical findings.
Main Results:
- Dominant emission bands were attributed to nonpolar and semipolar QWs, while a broad yellow-red band originated from GaN core defects.
- Emission from polar QWs at the NR tip was suppressed due to low photon state density and overshadowed by defect luminescence.
- Calculations confirmed lower photon state density at the NR tip, further limiting polar QW emission.
Conclusions:
- Defect-related luminescence and low photon state density at the NR tip are primary reasons for weak red emission from polar QWs.
- A proposed hybrid design, placing polar QWs in the cylindrical core with higher photon state density, can convert blue light to red light.
- This approach offers a viable solution to enhance red light generation, addressing a critical need for InGaN/GaN NRs in optoelectronic applications.
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