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Vehicle Exhaust Remote Sensing Device Method to Screen Vehicles for Evaporative Running Loss Emissions
Gary A Bishop1, Timothy H DeFries2, James A Sidebottom3
1Department of Chemistry and Biochemistry, University of Denver, Denver, Colorado 80208, United States.
Environmental Science & Technology
|November 6, 2020
Summary
Roadside exhaust sensors can detect evaporative hydrocarbon (HC) emissions by analyzing HC/carbon dioxide (CO2) correlations. This method identified a small percentage of vehicles, particularly older California LEV I models, emitting these non-tailpipe pollutants.
Area of Science:
- Environmental Science
- Atmospheric Chemistry
- Automotive Engineering
Background:
- Vehicle emissions contribute to air pollution, with both tailpipe and non-tailpipe sources.
- Understanding the apportionment of hydrocarbon (HC) emissions is crucial for effective air pollution control policies.
- Evaporative emissions, particularly running losses, represent a significant non-tailpipe source.
Purpose of the Study:
- To develop and apply a method for detecting evaporative running loss emissions using roadside exhaust sensors.
- To estimate the fleet-wide prevalence of evaporative running loss emissions.
- To identify vehicle types most associated with these emissions.
Main Methods:
- Utilized roadside exhaust sensor data measuring hydrocarbon (HC) and carbon dioxide (CO2).
- Defined a running loss index (RLI) based on the 90th percentile of HC/CO2 correlation residuals.
- Screened vehicle emission databases from West Los Angeles (2013, 2015) using the RLI method, identifying measurements exceeding three standard deviations above instrument noise.
Main Results:
- The RLI method successfully identified potential evaporative running loss emissions.
- An estimated 0.09% (2013) and 0.18% (2015) of measurements indicated evaporative running loss.
- California LEV I certified vehicles (1994-2003) were the predominant age group associated with these emissions.
- Instrument detection limits were significantly higher than federal standards.
Conclusions:
- Roadside exhaust sensors can be adapted to detect non-tailpipe evaporative HC emissions.
- Evaporative running loss emissions, though infrequent, are detectable in real-world vehicle fleets.
- Older vehicle fleets, specifically California LEV I models, show a higher propensity for these emissions, informing targeted policy interventions.

