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Related Concept Videos

Colors and Magnetism03:02

Colors and Magnetism

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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Solubility Equilibria03:07

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Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
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π Electron Effects on Chemical Shift: Overview01:27

π Electron Effects on Chemical Shift: Overview

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An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0,...
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Valence Bond Theory02:42

Valence Bond Theory

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Ferromagnetism01:31

Ferromagnetism

2.8K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.8K
Factors Affecting Solubility04:01

Factors Affecting Solubility

36.0K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation
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Magnetizing lead-free halide double perovskites.

Weihua Ning1, Jinke Bao2, Yuttapoom Puttisong1

  • 1Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping SE-581 83, Sweden.

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|November 7, 2020
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Summary

Researchers developed new lead-free double perovskites for spintronics by adding iron. These materials show magnetic properties, paving the way for advanced, low-power electronics.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Solid State Chemistry

Background:

  • Spintronics offers potential for high-speed, low-power information technology.
  • Lead halide perovskites (LHPs) show promise but their spin properties are limited by lead's spin-orbit coupling.
  • Developing novel magnetic materials is crucial for advancing spintronics.

Purpose of the Study:

  • To explore a new class of halide perovskites for spintronics applications.
  • To investigate the magnetic properties of iron-alloyed double perovskites.
  • To overcome the limitations of lead-based materials in spintronics.

Main Methods:

  • Alloying magnetic elements into optoelectronic double perovskites.
  • Synthesizing iron-alloyed double perovskite, Cs2Ag(Bi:Fe)Br6, where Fe3+ substitutes Bi3+.
  • Characterizing the magnetic response of the synthesized material.

Main Results:

  • Homogeneous distribution of FeBr6 clusters within the double perovskite crystals.
  • Observation of a strong temperature-dependent magnetic response below 30 K.
  • Tentative attribution of the magnetic response to weak ferromagnetic or antiferromagnetic ordering.

Conclusions:

  • Demonstrated a new approach to create spintronic materials using lead-free double perovskites.
  • The iron-alloyed double perovskite exhibits promising magnetic properties.
  • This work encourages further research into lead-free double perovskites for spintronics.