Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

X-ray Diffraction of Biological Samples01:10

X-ray Diffraction of Biological Samples

4.4K
X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
According to Bragg's law, when X-rays strike the sample positioned on a stage, the rays are  scattered by the electron clouds around the sample atoms. The  X-ray diffraction or scattering is caused by constructive interference of the X-ray waves that reflect off the internal...
4.4K
X-ray Crystallography02:18

X-ray Crystallography

25.3K
The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...
25.3K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Rate-Dependent Anisotropic Lattice Strain in LiFePO<sub>4</sub> Verified by Simultaneous <i>Operando</i> X-ray Diffraction and Absorption Measurements.

Inorganic chemistry·2026
Same author

Nondestructive Chemical Mapping of Lithium on/in a Graphite Electrode via X‑ray Raman Scattering Spectroscopy.

ACS omega·2026
Same author

Mechanism of CO<sub>2</sub> Electrolysis with Heterogenized Molecular Iridium Catalysts Deciphered Using Operando Spectroscopy.

Journal of the American Chemical Society·2025
Same author

Direct observation of an ionic cobalt complex electron mediator <i>via operando</i> X-ray absorption spectroscopy in photocatalytic Z-scheme CO<sub>2</sub> reduction with (CuGa)<sub>0.3</sub>Zn<sub>1.4</sub>S<sub>2</sub> and BiVO<sub>4</sub>.

Chemical communications (Cambridge, England)·2025
Same author

Sustainable Recovery of Lithium from Contaminated Soil through Halophyte Salt Excretion.

Environmental science & technology·2025
Same author

Electrochemical CO<sub>2</sub> Fixation and Release Cycle Featuring a Trinuclear Zinc Complex for Direct Air Capture.

Angewandte Chemie (International ed. in English)·2024

Related Experiment Video

Updated: Dec 1, 2025

Biochemical and Structural Characterization of the Carbohydrate Transport Substrate-binding-protein SP0092
08:53

Biochemical and Structural Characterization of the Carbohydrate Transport Substrate-binding-protein SP0092

Published on: October 2, 2017

31.1K

Operando X-ray Diffraction and Double-Edge X-ray Absorption Spectroscopy Studies on a Perfect Zero-Strain Material.

Kazuhiko Mukai1, Takamasa Nonaka1, Takeshi Uyama1

  • 1Toyota Central Research and Development Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi 480-1192, Japan.

Inorganic Chemistry
|November 9, 2020
PubMed
Summary

Researchers visualized the reaction mechanism of zero-strain materials for lithium-ion batteries. Operando X-ray diffraction and spectroscopy revealed atomic-scale structural changes during charge-discharge cycles.

More Related Videos

High Pressure Single Crystal Diffraction at PX^2
11:32

High Pressure Single Crystal Diffraction at PX^2

Published on: January 16, 2017

21.9K
Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

2.5K

Related Experiment Videos

Last Updated: Dec 1, 2025

Biochemical and Structural Characterization of the Carbohydrate Transport Substrate-binding-protein SP0092
08:53

Biochemical and Structural Characterization of the Carbohydrate Transport Substrate-binding-protein SP0092

Published on: October 2, 2017

31.1K
High Pressure Single Crystal Diffraction at PX^2
11:32

High Pressure Single Crystal Diffraction at PX^2

Published on: January 16, 2017

21.9K
Determining the Mechanical Strength of Ultra-Fine-Grained Metals
05:04

Determining the Mechanical Strength of Ultra-Fine-Grained Metals

Published on: November 22, 2021

2.5K

Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-state Chemistry

Background:

  • Zero-strain insertion materials are critical for high-performance lithium-ion batteries.
  • Experimental determination of local structural changes in these materials is challenging.

Purpose of the Study:

  • To visualize the reaction scheme of a perfect zero-strain material, (Li0.75Zn0.25)[Li0.417Ti1.583]O4, with a spinel framework.
  • To understand atomic-scale structural variations during battery operation.

Main Methods:

  • Utilized operando X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS).
  • Employed a tapered undulator and monochromator system for advanced operando measurements.
  • Collected a series of XRD, Ti K-edge XAS, and Zn K-edge XAS data.

Main Results:

  • Successfully visualized the reaction scheme of the zero-strain material.
  • Unveiled drastic atomic-scale structural variations between charge and discharge, including changes in lattice parameter, bond distances, and Zn2+ ion occupancy.
  • Observed discrepancies with previous ex situ studies indicating immutable lattice parameters.

Conclusions:

  • Operando XRD/XAS provides dynamic information under operating conditions.
  • This technique is valuable for understanding zero-strain reaction mechanisms.
  • Findings can guide the design of advanced zero-strain insertion materials with improved energy density.