Microstructural and rheological investigation of upcycled metal-organic frameworks stabilized Pickering emulsions

Stabilizing Pickering emulsions with metal-organic frameworks (MOFs) is a known way to incorporate them into hierarchically porous materials. Studies generally focus on their final properties and emulsion microstructures are rarely precisely described. Our hypothesis was that characterizing the microstructural and rheological properties of Pickering emulsions stabilized solely by Al-based MOFs (MIL-96) particles would provide insights into how to control their stability and workability for potential industrial applications.

MIL-96(Al) particles, obtained from Li-ion battery waste were used to stabilize paraffin-in-water Pickering emulsions. The influence of the formulation parameters (paraffin/water volume ratio and MIL-96(Al) content) were investigated and the emulsions were analysed using optical microscopy, cryo-scanning electron microscopy and rheological measurements.

MIL-96(Al) efficiently stabilized paraffin-in-water emulsions with up to 80% of internal phase. The emulsions with a low paraffin volume fraction had large droplets and a fluid gel-like texture. The emulsions with higher paraffin volume fractions were more compact and had two-step flow curves. In this system, excess MIL-96(Al) particles aggregated in the continuous phase as flocs interact with particles adsorbed at the paraffin-water interface, creating a secondary network that has to be broken for flow to resume. This behaviour may be interesting to investigate in other MOF-stabilized emulsions.