Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane
Patrick Zwick1, Chunwei Hsu2, Maria El Abbassi2
1Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland.
Abstract:
Porphyrin cyclophane 1, consisting of two rigidly fixed but still movable cofacial porphyrins and exposing acetate-masked thiols in opposed directions of the macrocycle, is designed, synthesized, and characterized. The functional cyclophane 1, as pioneer of mechanosensitive 3D materials, forms stable single-molecule junctions in a mechanically controlled break-junction setup. Its reliable integration in a single-molecule junction is a fundamental prerequisite to explore the potential of these structures as mechanically triggered functional units and devices.
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