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Related Experiment Video

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Characterization of Surface Modifications by White Light Interferometry: Applications in Ion Sputtering, Laser Ablation, and Tribology Experiments
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Influence of sample surface topography on laser ablation process.

Zita Salajková1, Markéta Holá2, David Prochazka3

  • 1Materials Characterization and Advanced Coatings, Central European Institute of Technology, Purkyňova 656/123, Brno, Czech Republic; Department of Chemistry, University of Bari, Via Orabona 4, 70126, Bari, Italy.

Talanta
|November 10, 2020
PubMed
Summary

Sample surface topography significantly impacts laser ablation (LA) and LA Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) analysis. Roughening surfaces enhances signal intensity, but can also alter elemental fractionation, requiring careful sample preparation for accurate results.

Keywords:
FractionationLA-ICP-MSLaser ablationSurface analysisSurface topography

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Area of Science:

  • Analytical Chemistry
  • Materials Science
  • Geochemistry

Background:

  • Sample surface topography is a critical, yet often overlooked, factor in laser ablation (LA) processes.
  • The analytical accuracy of LA coupled with Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) can be profoundly affected by surface characteristics.

Purpose of the Study:

  • To investigate the influence of varying sample surface topographies on the LA-ICP-MS analytical response.
  • To quantify the impact of surface roughness on signal intensity and elemental fractionation.

Main Methods:

  • Prepared six distinct surface topographies on certified aluminum alloy (BAM 311) and NIST 610 reference materials.
  • Performed repetitive LA-ICP-MS measurements across a laser fluence range of 1-13 J/cm².
  • Analyzed spot-by-spot data to assess signal amplification and elemental fractionation.

Main Results:

  • Increased surface roughness led to significant amplification of the ICP-MS signal for most measured isotopes.
  • An enhancement of over sixty times was observed on the aluminum alloy sample compared to its polished surface.
  • Surface topography was found to influence elemental fractionation, altering the relative signals of different elements.

Conclusions:

  • Sample surface topography significantly impacts LA-ICP-MS results, affecting both signal intensity and elemental fractionation.
  • Variations in surface preparation can lead to misleading data interpretation, even with ablation preshots.
  • Careful surface preparation is essential for accurate single-shot analysis and chemical mapping; surface roughening can enhance sensitivity and suppress matrix effects.