Defect enrich ultrathin TiO₂ nanosheets for rapid adsorption and visible light mediated PPCPs degradation

Recently, PPCPs have attracted extensive attention as emerging pollutants. Due to the strong hydrophilicity and small molecular weight, PPCPs are difficult to be fully removed by adsorption and other processes, posing a serious threat to the ecological environment. Here, we demonstrate solvothermal synthesis of defect enrich TiO₂ nanosheets through simple copper doping. Novel TiO₂ nanosheets were found to be mesoporous with high specific surface area and exhibited excellent visible light response. Performance of the developed TiO₂ nanosheets were evaluated towards photocatalytic degradation of two model pollutants, tetracycline and acetaminophen. Results showed robust degradation of tetracycline and acetaminophen under visible-light irradiation within 100 min. Meanwhile, the potential relationship between the structural characteristics and excellent ability of the catalyst was discussed, as well as probable mechanism. Additionally, a study on the toxicity of tetracycline solution to human skin epidermal cells showed that the toxicity of the treated solution to cells is greatly reduced. The prepared catalysts show good repeatability (a slightly decrease ca.3% after 5 cycles) and applicability, providing a reasonable design for water remediation.