The Zeeman, spin-orbit, and quantum spin Hall interactions in anisotropic and low-dimensional conductors

To construct a microscopic theory of electrons and holes in anisotropic conductors that self-consistently treats their band effective mass anisotropy with their interactions with applied electric and magnetic fields, the Dirac equation is extended for an electron or hole in an orthorhombically-anisotropic conduction band. Its covariance is established both by a modified version of the Klemm-Clem transformations to a space in which it is isotropic, and also in its fully anisotropic form by making the most general proper and improper Lorentz transformations, proving its validity in both the relativistic and non-relativistic limits. The appropriate Foldy-Wouthuysen transformations are extended to expand about the non-relativistic Hamiltonian limit to fourth order in the inverse of the particle's Einstein rest energy. The results have important consequences for magnetic measurements of many classes of clean anisotropic semiconductors, metals, and superconductors. In all of these cases, the Zeeman interaction is found to depend strongly upon the effective mass anisotropy. When an electron or hole is traveling in an atomically thin one-dimensional conduction band, its Zeeman, spin-orbit, and quantum spin Hall interactions are vanishingly small. Accurate expressions for the Zeeman, spin-orbit and quantum spin Hall interactions for two-dimensional conductors are provided.