Cobalt phosphide (Co2P) encapsulated in nitrogen-rich hollow carbon nanocages with fast rate potassium ion storage
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Updated: Nov 30, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Debanjan Das1, Debasish Sarkar2, Sudhan Nagarajan3
1Materials Research Centre, Indian Institute of Science, Bengaluru-560012, India.
Abstract:
We synthesized Co2P nanoparticle encapsulated N-doped carbon nanocages through one-step carbonization-phosphidation of ZIF-67. As potassium ion battery (KIB, PIB) anodes, the Co2P@NCCs display state-of-the-art electrochemical performance, including the most favorable fast charge characteristics reported. The single-nanometer thick carbon cage yields rapid solid-state K-ion diffusion and prevents aggregation/pulverization of 40 nm cobalt phosphide.
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