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Updated: Nov 30, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
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Published on: August 6, 2018

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Vibrationally Hot and Cold Triplets. Sensitizer-Dependent Dynamics and Localized Vibrational Promotion of a

Kai-Yuan Kuan1, Daniel A Singleton1

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, United States.

Journal of the American Chemical Society
|November 12, 2020
PubMed
Summary

Large intramolecular kinetic isotope effects (KIEs) in benzobarrelene rearrangement align with heavy-atom tunneling using low-energy sensitizers. Higher-energy sensitizers yield lower KIEs, indicating hot, nonstatistical dynamics from excess vibrational energy.

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