Radiation Induced Surface Modification of Nanoparticles and their Dispersion in the Polymer Matrix

Polymer grafted inorganic nanoparticles attract significant attention, but pose challenges because of the complexity. In this work, a facile strategy to the graft polymer onto the surface of nanoparticles have been introduced. The vinyl functionalized SiO₂ nanoparticles (NPs) were first prepared by the surface modification of the unmodified SiO₂ using γ-methacryloxy propyl-trimethoxylsilane. The NPs were then mixed with polyvinylidene fluoride (PVDF), which was followed by the Co-60 Gamma radiation at room temperature. PVDF molecular chains were chemically grafted onto the surface of SiO₂ nanoparticles by the linking of the double bond on the NPs. The graft ratio of PVDF on SiO₂ NPs surface can be precisely controlled by adjusting the absorbed dose and reactant feed ratio (maximum graft ratio was 31.3 wt%). The strategy is simple and it should be applied to the surface modification of many other nanoparticles. The prepared PVDF-grafted SiO₂ NPs were then dispersed in the PVDF matrix to make the nanocomposites. It was found that the modified NPs can be precisely dispersed into the PVDF matrix, as compared with pristine silica. The filling content of modifications SiO₂ NPs on the PVDF nanocomposites is almost doubled than the pristine SiO₂ counterpart. Accordingly, the mechanical property of the nanocomposites is significantly improved.