Co/Sm-modified Ti/PbO₂ anode for atrazine degradation: Effective electrocatalytic performance and degradation...

In this work, Ti/PbO₂-Co-Sm electrode has been successfully prepared using electrodeposition and further applied for the electrocatalysis of atrazine (ATZ) herbicide wastewater. As expected, Ti/PbO₂-Co-Sm electrode displays highest oxygen evolution potential, lowest charge transfer resistance, longest service lifetime and most effective electrocatalytic activity compared with Ti/PbO₂, Ti/PbO₂-Sm and Ti/PbO₂-Co electrodes. Orthogonal and single factor experiments are designed to optimize the condition of ATZ degradation. The maximum degradation efficiency of 92.6% and COD removal efficiency of 84.5% are achieved in electrolysis time 3 h under the optimum condition (current density 20 mA cm^-2, Na₂SO₄ concentration 8.0 g L^-1, pH 5 and temperature 35 °C). In addition, Ti/PbO₂-Co-Sm electrode exhibits admirable recyclability in degradation progress. The degradation of ATZ is accomplished by indirect electrochemical oxidation and ∙OH is tested as the main active substance in ATZ oxidation. The possible degradation mechanism of ATZ has been proposed according to the degradation intermediates detected by LC-MS. This research suggests that Ti/PbO₂-Co-Sm is a promising electrode for ATZ degradation.