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Updated: Nov 30, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Fixation stability of glass matrix co-existent with crystal phases for heavy metals formed by high-temperature
Lanyu Hu1, Jianlong Ma1, Yang Yue2
1SHU Center of Green Urban Mining & Industry Ecology, School of Environmental and Chemical Engineering, Shanghai University, No. 381 Nanchen Road, Shanghai, 200444, People's Republic of China.
Abstract:
Vitrification is an effective solidification method for heavy metal-containing wastes. However, most investigations focused on the formation of glass matrix. Seldom report discussed the influence of co-existing crystals on heavy metal stabilizations. In this work, Ca-Al-Si phase was formed in the glass matrix by adjusting the composition of feeding ingredient and melting temperature. As a result, when molar ratio of CaO/(SiO2+Al2O3) was lower than 0.97 and reaction temperature was bigger than 1300 °C, small-size Ca-Al-Si phase (Ca2Al2SiO7 and CaAl2Si2O8) was homogeneously distributed in vitreous matrix. At the same time, Cr, Zn, and Pb leaching concentrations were the lowest, far lower than the leaching standard values. According to theoretical calculations, Zn and Pb replaced Ca atom; Cr replaced Al atom in Ca-Al-Si phase under thermal conditions. These replacements resulted in the fixation and stabilization of heavy metals. When the CaO/(SiO2+Al2O3) molar ratio was bigger than 1.00, neither glass nor Ca-Al-Si was formed. Similarly, when the melting temperature was decreased, Ca-Al-Si phase formed a bigger size. Both these went against the stabilization, resulting in high leaching concentrations of heavy metals. The main of this work will help the development of high-temperature melting for the treatment of hazardous wastes.
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