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Atomic-Scale Imprinting by Sputter Deposition of Amorphous Metallic Films
Zheng Chen1, Amit Datye1, Georg H Simon1
1Department of Mechanical Engineering and Materials Science, Yale University, New Haven, Connecticut 06511, United States.
ACS Applied Materials & Interfaces
|November 16, 2020
Summary
A new sputter deposition method enables atomic-scale imprinting on a wide range of bulk metallic glasses (BMGs), overcoming limitations of traditional nanoimprinting. This versatile technique allows for precise surface structuring and functionalization at the atomic level.
Area of Science:
- Materials Science
- Nanotechnology
- Surface Engineering
Background:
- Nanoimprinting fabricates structures for diverse applications but struggles with subnanometer precision.
- Bulk metallic glasses (BMGs) offer potential for atomic-scale imprinting via thermoplastic forming (TPF) due to their lack of an intrinsic length scale.
- Current TPF methods for BMGs are limited to a narrow range of alloys.
Purpose of the Study:
- To develop a novel method for atomic-scale imprinting applicable to a broad spectrum of amorphous alloys.
- To overcome the limitations of existing nanoimprinting techniques for achieving ultraprecise patterns.
- To establish a versatile and practical approach for atomic-scale surface structuring and functionalization.
Main Methods:
- A sputter deposition-based approach was developed for replicating atomic-scale features.
- The method was tested for its applicability to a wide range of amorphous alloys.
- Evaluation of the method's scalability, mold compatibility, and material efficiency.
Main Results:
- The sputter deposition method successfully replicated atomic-scale features on various amorphous alloys, significantly broadening material compatibility.
- The technique demonstrated scalability and the ability to replicate diverse mold structures.
- Low material consumption and ease of application onto various workpieces were confirmed.
Conclusions:
- The developed sputter deposition method offers a practical and versatile alternative for atomic-scale imprinting, extending beyond the limitations of TPF.
- This advancement opens new possibilities for atomically defined surface structuring and functionalization across a wide range of materials.
- The technique represents a significant step towards a practical toolbox for atomic-scale imprinting in science and technology.

